CAS 108-32-7  ·  C₄H₆O₃  ·  MW 102.09 g/mol  ·  BP 241.7°C

Propylene Carbonate (PC) — U.S. Supplier

Industrial and battery-grade propylene carbonate for the U.S. market. High-boiling, high-dielectric cyclic carbonate solvent used in Li-ion and Na-ion battery electrolytes, Fluor Solvent CO₂ scrubbing, NMP replacement, and cosmetics. Non-flammable under DOT — flash point 132°C. COA, SDS, and full traceability with every order.

PC 4-Methyl-1,3-dioxolan-2-one 1,2-Propylene carbonate Carbonic acid propylene ester Cyclic propylene carbonate CAS 108-32-7
108-32-7
CAS Number
102.09
Mol. Weight (g/mol)
241.7°C
Boiling Point
132°C
Flash Point
1.204 g/mL
Density @ 20°C
ε = 65.0
Dielectric Constant

Available Grades of Propylene Carbonate

Industrial and battery purity tiers — each grade ships with a lot-specific certificate of analysis.

Grade 1
Industrial / Technical Grade
Gas scrubbing · Industrial solvent · Cosmetics · NMP replacement
Assay (GC)≥99.5%
Moisture (KF)≤500 ppm
Acidity≤0.01%
Color (APHA)≤10
Propylene glycol≤0.1%
Non-volatile residue≤0.02%
Grade 2 — High Demand
Battery / Electronic Grade
Li-ion electrolytes · Na-ion batteries · Electrochemistry
Assay (GC)≥99.9%
Moisture (KF)≤50 ppm
Acidity≤5 ppm
Total metals≤1 ppm each
Color (APHA)≤5
Non-volatile residue≤5 ppm

Physical & Chemical Properties

Identification
Chemical NamePropylene Carbonate
AbbreviationPC
CAS Number108-32-7
Molecular FormulaC₄H₆O₃
Molecular Weight102.09 g/mol
EINECS Number203-572-1
TSCA StatusListed on TSCA inventory
Transport ClassCombustible liquid (flash point >60°C; not DOT Class 3)
Physical Properties
AppearanceColorless to pale yellow liquid
Boiling Point241.7°C (467°F)
Melting Point-48.8°C (-56°F)
Flash Point132°C (270°F, closed cup)
Density @ 20°C1.204 g/mL (10.04 lb/gal)
Viscosity @ 25°C2.5 mPa·s
Dielectric Constant @ 25°C65.0
Refractive Index (n20/D)1.4189
Vapor Pressure @ 20°C<0.1 hPa
Water Solubility~17% (partially miscible)

What Is Propylene Carbonate Used For?

PC combines high boiling point, high dielectric constant, very low vapor pressure, and non-flammable handling — making it valuable in battery, industrial, and specialty chemical applications.

Sodium-Ion & Lithium-Ion Battery Electrolytes

Propylene carbonate is a key electrolyte co-solvent in sodium-ion (Na-ion) and specialty lithium-ion battery applications. Its high dielectric constant (ε=65) enables strong salt dissociation and ionic conductivity with NaPF₆ and LiPF₆ electrolyte salts. PC's wide liquid range (-49°C to 242°C) supports extreme-temperature operation. In sodium-ion batteries with hard-carbon anodes, PC is electrochemically compatible and does not cause the co-intercalation and anode exfoliation that EC can cause with graphite in Li-ion cells. Battery-grade PC (≥99.9%, moisture ≤50 ppm, metals ≤1 ppm) is required for electrolyte applications.

Fluor Solvent Process — CO₂ & Acid Gas Scrubbing

The Fluor Solvent process (licensed by Fluor Corporation) uses propylene carbonate as the physical absorption solvent to remove CO₂, H₂S, COS, and other acid gases from natural gas, synthesis gas, and industrial streams. PC is selected because of its high acid-gas solubility, very low vapor pressure (minimal solvent losses), chemical inertness under process conditions, non-corrosive behavior, and easy regeneration by pressure let-down — no thermal regeneration required. PC absorbs selectively and recovers cleanly, making the process highly energy-efficient compared to chemical scrubbing with amines.

Industrial Solvent — NMP and DCM Replacement

Propylene carbonate is increasingly adopted as a safer industrial solvent to replace NMP (N-methylpyrrolidone) and DCM (dichloromethane). NMP is classified as a reproductive toxicant under EU REACH and subject to strict use restrictions — PC offers comparable solvating power for PVDF, polyimides, and polar polymers without the reproductive hazard classification. Unlike DCM, PC contains no chlorine and generates no halogen waste streams. PC's very low vapor pressure (<0.1 hPa) reduces evaporative losses and workplace inhalation exposure, and its 132°C flash point eliminates flammability concerns during processing.

Cosmetics & Personal Care

Propylene carbonate is an INCI-listed cosmetic ingredient used as a solvent, carrier, and solubilizing agent in sunscreens, serums, hair care, and aerosol formulations. Its low volatility, near-odorless character, good skin tolerability, and solvating power for UV filters, vitamins, and lipophilic actives make it practical for leave-on and rinse-off cosmetic systems. PC is approved under the EU Cosmetics Regulation and widely referenced in international INCI formulations.

Handling advantage — non-flammable under DOT: With a flash point of 132°C, propylene carbonate is not classified as a DOT hazardous material for transport. This dramatically simplifies logistics compared to low-flash carbonate solvents (DMC, EMC, DEC). Standard non-hazmat carriers can ship PC, reducing freight complexity and cost at scale.

Propylene Carbonate Packaging Options

From R&D samples to bulk quantities. Contact us for pricing, MOQ, and lead times.

🧪
Sample / R&D
Evaluation quantities
🪣
5-Gallon Pail
~19 liters
🛢️
55-Gallon Drum
208 L steel drum
📦
IBC / Tote
275–330 gallon
🚛
Bulk Tanker
TL / LTL quantities

Documents Available for PC

All documentation available on request via the quote form below.

📄
Safety Data Sheet (SDS)
GHS-formatted · Combustible liquid
📋
Certificate of Analysis (COA)
Lot-specific · All QC parameters
📊
Technical Data Sheet (TDS)
Physical and chemical properties
TSCA Compliance
CAS 108-32-7 on TSCA inventory

Regulatory Status

TSCA ListedCAS 108-32-7 on TSCA inventory
Not DOT HazardousFlash point 132°C — no Class 3 restriction
INCI ListedPropylene Carbonate (cosmetics use)
U.S. Import CompliantFull chain-of-custody documentation

Frequently Asked Questions — Propylene Carbonate

What is propylene carbonate (PC)?

Propylene carbonate (CAS 108-32-7) is a cyclic organic carbonate with formula C₄H₆O₃ and MW 102.09 g/mol. It is a colorless, high-boiling liquid (BP 241.7°C) with a high dielectric constant (ε=65.0), very low vapor pressure, and flash point of 132°C. PC is used as a battery electrolyte co-solvent, industrial solvent (NMP/DCM replacement), CO₂ absorption solvent (Fluor Solvent process), and cosmetics ingredient.

Is propylene carbonate used in sodium-ion batteries?

Yes — PC is particularly well-suited for sodium-ion (Na-ion) electrolytes. Hard-carbon Na-ion anodes are electrochemically compatible with PC, unlike graphite/Li-ion systems where PC can cause co-intercalation and exfoliation. PC's high dielectric constant aids NaPF₆ dissolution and its wide liquid temperature range supports broad operating conditions. As Na-ion batteries scale for grid storage and low-cost EVs, PC is a primary electrolyte component.

What does the "Fluor Solvent" process use PC for?

The Fluor Solvent process is a physical gas sweetening technology that uses propylene carbonate to absorb CO₂, H₂S, and acid gases from high-pressure gas streams. PC is chosen for its high acid-gas solubility, minimal vapor pressure (low solvent loss), chemical stability, and ability to regenerate simply by pressure reduction — with no heat input required. It is widely used in natural gas processing and syngas purification plants globally.

Is propylene carbonate hazardous to ship?

No — propylene carbonate is not classified as a DOT hazardous material. Its flash point of 132°C is well above the 60°C threshold for flammable liquids. Standard non-hazmat freight carriers can handle PC shipments, reducing logistics complexity and cost compared to low-flash-point carbonate solvents like DMC, EMC, or DEC.

Can PC replace NMP in PVDF electrode manufacturing?

Yes. PC is a lower-toxicity solvent for PVDF binder systems used in Li-ion battery electrode manufacturing — the primary NMP application. PC offers comparable PVDF dissolution without NMP's reproductive toxicity concerns (EU REACH SVHC). Its high boiling point and low vapor pressure also reduce evaporative losses and allow efficient solvent recovery in closed-loop systems.

What packaging is available for propylene carbonate?

CARMELSOLV™ supplies PC in sample/R&D quantities, 5-gallon pails, 55-gallon (208L) steel drums, 275–330 gallon IBC totes, and bulk tanker quantities. Contact us for current pricing and lead times for your required volume and grade.

Is propylene carbonate TSCA listed?

Yes. CAS 108-32-7 is listed on the U.S. EPA TSCA Chemical Substance Inventory and is fully compliant for commercial import and distribution in the United States. CARMELSOLV™ imports and distributes PC in full compliance with U.S. import and chemical regulations.

Request a Quote — Propylene Carbonate

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